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Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline

Received: 25 May 2021    Accepted: 11 June 2021    Published: 25 June 2021
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Abstract

The paper aims to study the effect of temperature on wax deposition on corrosion of crude oil pipeline at different flow rate with time. The waxy crude oil sample is pumped into the design and fabricated experimental flow-loop set up under different operating conditions. The effect of temperature on corrosion at different flow rate of wax deposition during the corrosion inhibition were studied at flow rate of 10.21, 20.37, 30.45, 40.28 and 50.70 L/min and time at 3, 6, 9, 12, 15 and 18 min while keeping temperature constant for each of the experimental run at 15, 20, 25, 30 and 35°C, to determine the corrosion rate against time. The results showed that at flow rate of 10.21 L/min and time 18 min at constant temperature of 15°C, the corrosion rate is 0.11 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 20°C, the corrosion rate is 0.08 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 25°C, the, corrosion rate is 0.12 mpy. Based on the results, a significant reduction of corrosion rates and excellent corrosion protection is achieved while others provided only moderate or negligible protection to the crude oil pipeline. However, the wax layer becomes thicker with time, if the temperature stays below the WAT for extended period of time and can in the long run, cause partial or total blockage of the pipe. Hence, as the deposition of the paraffin wax increases the corrosion rate decrease. The paraffin wax film presence on the surface promotes a significant reduction of general corrosion rates on the pipeline, although localized corrosion was observed due to loss of integrity of the paraffin layer. It means that deposition of paraffin wax inhibit corrosion and also give protection to the pipeline layer. Finally, due to the long chain paraffin layer being physically removed from the surface most of the corrosion protection has been lost during the periods of increased flow rate or temperature.

Published in American Journal of Mechanical and Materials Engineering (Volume 5, Issue 2)
DOI 10.11648/j.ajmme.20210502.12
Page(s) 29-34
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Temperature, Wax Deposition, Corrosion Rate

References
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[3] Simmons, M. (2008). "Oil and Gas “Rust”: An Evil Worse Than Depletion", in Offshore Technology Conference (OTC) Presentation, National Association of Corrosion Engineers.
[4] Morales, J. L. Perdomo, J. J. Ramirez, M. and Viloria, A. (2000) "Effect of Crude Oil Contaminants on the Internal Corrosion in Gas Pipelines", CORROSION, paper no. 00040 (Houston, TX: National Association Corrosion Engineers).
[5] Alsabagh, A. M, Migahed, M. A, HayamAwad, S. (2006). Reactivity of polyester aliphatic amine surfactants as corrosion inhibitors for carbon steel in formation water (deep well water), Corrosion Science, 48, 813.
[6] Bentiss, F, Lagrenée M., Traisnel M. (2000). 5-Bis(n-Pyridyl)-1,3,4-Oxadiazoles as Corrosion Inhibitors for Mild Steel in Acidic Media, Corrosion, 56, 733. Journal of Corrosion Science, 42, 127.
[7] Deyab, M. A. (2007). Effect of cationic surfactant and inorganic anions on the Electro-chemical behavior of carbon steel in formation water, Journal of Corrosion Science.
[8] Kermani, M. B, Morshed A. (2003). Carbon Dioxide Corrosion in Oil and Gas Production. A Compendium, Corrosion, 59, 659.
[9] Lebrini, M, Traisnel M, Lagrene M, Mernari B, Bentiss F. (2007). Inhibitive properties, adsorption and a theoretical study of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles as corrosion inhibitors for mild steel in perchloric acid, Journal of Corrosion Science, 50, 473.
[10] Morad, M. S. Kamal, El-Dean A. M. (2006). 2,2'-Dithiobis(3-cyano-4,6-dimethylpyridine): A new class of acid corrosion inhibitors for mild steel, Journal Corrosion of Science, 48, 3398.
[11] Nesic S. (2007). Key issues related to modelling of internal corrosion of oil and gas pipelines-A review', Corrosion Science, volume. 49, 12, 4308-4338.
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[14] Shein, A. B., Denisova A. V. (2006). Choice of Effective Corrosion Inhibitors for Acid Treatment of Wells, Protection of Metals, 42, 34.
[15] Smith, L. (1999). Control of corrosion in oil and gas production tubing, Br. Corrosion Journal, 34 (247).
[16] Villamizar, W. Casales, M. J. Gonzalez-Rodriguez, G. Martinez, L. (2007). CO2 corrosion inhibition by hydroxyethyl, aminoethyl, and amidoethylimidazolines in water–oil mixtures, Journal of Solid State Electrochemistry, 11, 619.
[17] Mohammed, Z. (2007). Industrial and Engineering Chemistry Research, American Conference Institute., 46: 14.
[18] Lund, H. (1998). Investigation of Paraffin Deposition during Single Phase Flow. M S Thesis. The University of Tulsa, Tulsa, OK.
[19] Haq, M. A. (1978). Deposition of Paraffin Wax from Its Solution with Hydrocarbons.
[20] Cole, R and Jessen F. FW. (1960). Paraffin Deposition', Oil Gas Journal, 58, 38-87.
[21] Tang, N. L., Hwu W. L., Chan, R. T., Law, L. K., Fung, L. M. and Zhang, W. M. (2002). A founder mutation (R254X) of SLC22A5 (OCTN2). Hum. Mutat., 20 (3): 232.
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[24] Jennings, D. W. and Weispfennig, K. (2005). Effect of Shear and Temperature on Wax Deposition: Cold-finger investigation with a Gulf of Mexico Crude Oil, Energy and Fuels, 19, 1376-1386.
Cite This Article
  • APA Style

    Nnorom Obinichi, Alexander Nwachukwu Okpala, Tolumoye Johnnie Tuaweri. (2021). Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline. American Journal of Mechanical and Materials Engineering, 5(2), 29-34. https://doi.org/10.11648/j.ajmme.20210502.12

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    ACS Style

    Nnorom Obinichi; Alexander Nwachukwu Okpala; Tolumoye Johnnie Tuaweri. Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline. Am. J. Mech. Mater. Eng. 2021, 5(2), 29-34. doi: 10.11648/j.ajmme.20210502.12

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    AMA Style

    Nnorom Obinichi, Alexander Nwachukwu Okpala, Tolumoye Johnnie Tuaweri. Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline. Am J Mech Mater Eng. 2021;5(2):29-34. doi: 10.11648/j.ajmme.20210502.12

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  • @article{10.11648/j.ajmme.20210502.12,
      author = {Nnorom Obinichi and Alexander Nwachukwu Okpala and Tolumoye Johnnie Tuaweri},
      title = {Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline},
      journal = {American Journal of Mechanical and Materials Engineering},
      volume = {5},
      number = {2},
      pages = {29-34},
      doi = {10.11648/j.ajmme.20210502.12},
      url = {https://doi.org/10.11648/j.ajmme.20210502.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmme.20210502.12},
      abstract = {The paper aims to study the effect of temperature on wax deposition on corrosion of crude oil pipeline at different flow rate with time. The waxy crude oil sample is pumped into the design and fabricated experimental flow-loop set up under different operating conditions. The effect of temperature on corrosion at different flow rate of wax deposition during the corrosion inhibition were studied at flow rate of 10.21, 20.37, 30.45, 40.28 and 50.70 L/min and time at 3, 6, 9, 12, 15 and 18 min while keeping temperature constant for each of the experimental run at 15, 20, 25, 30 and 35°C, to determine the corrosion rate against time. The results showed that at flow rate of 10.21 L/min and time 18 min at constant temperature of 15°C, the corrosion rate is 0.11 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 20°C, the corrosion rate is 0.08 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 25°C, the, corrosion rate is 0.12 mpy. Based on the results, a significant reduction of corrosion rates and excellent corrosion protection is achieved while others provided only moderate or negligible protection to the crude oil pipeline. However, the wax layer becomes thicker with time, if the temperature stays below the WAT for extended period of time and can in the long run, cause partial or total blockage of the pipe. Hence, as the deposition of the paraffin wax increases the corrosion rate decrease. The paraffin wax film presence on the surface promotes a significant reduction of general corrosion rates on the pipeline, although localized corrosion was observed due to loss of integrity of the paraffin layer. It means that deposition of paraffin wax inhibit corrosion and also give protection to the pipeline layer. Finally, due to the long chain paraffin layer being physically removed from the surface most of the corrosion protection has been lost during the periods of increased flow rate or temperature.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Influence of Temperature on Wax Deposit on Corrosion of Crude Oil Pipeline
    AU  - Nnorom Obinichi
    AU  - Alexander Nwachukwu Okpala
    AU  - Tolumoye Johnnie Tuaweri
    Y1  - 2021/06/25
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajmme.20210502.12
    DO  - 10.11648/j.ajmme.20210502.12
    T2  - American Journal of Mechanical and Materials Engineering
    JF  - American Journal of Mechanical and Materials Engineering
    JO  - American Journal of Mechanical and Materials Engineering
    SP  - 29
    EP  - 34
    PB  - Science Publishing Group
    SN  - 2639-9652
    UR  - https://doi.org/10.11648/j.ajmme.20210502.12
    AB  - The paper aims to study the effect of temperature on wax deposition on corrosion of crude oil pipeline at different flow rate with time. The waxy crude oil sample is pumped into the design and fabricated experimental flow-loop set up under different operating conditions. The effect of temperature on corrosion at different flow rate of wax deposition during the corrosion inhibition were studied at flow rate of 10.21, 20.37, 30.45, 40.28 and 50.70 L/min and time at 3, 6, 9, 12, 15 and 18 min while keeping temperature constant for each of the experimental run at 15, 20, 25, 30 and 35°C, to determine the corrosion rate against time. The results showed that at flow rate of 10.21 L/min and time 18 min at constant temperature of 15°C, the corrosion rate is 0.11 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 20°C, the corrosion rate is 0.08 mpy. At flow rate of 10.21 L/min and time 18 min at constant temperature of 25°C, the, corrosion rate is 0.12 mpy. Based on the results, a significant reduction of corrosion rates and excellent corrosion protection is achieved while others provided only moderate or negligible protection to the crude oil pipeline. However, the wax layer becomes thicker with time, if the temperature stays below the WAT for extended period of time and can in the long run, cause partial or total blockage of the pipe. Hence, as the deposition of the paraffin wax increases the corrosion rate decrease. The paraffin wax film presence on the surface promotes a significant reduction of general corrosion rates on the pipeline, although localized corrosion was observed due to loss of integrity of the paraffin layer. It means that deposition of paraffin wax inhibit corrosion and also give protection to the pipeline layer. Finally, due to the long chain paraffin layer being physically removed from the surface most of the corrosion protection has been lost during the periods of increased flow rate or temperature.
    VL  - 5
    IS  - 2
    ER  - 

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Author Information
  • Mechanical Engineering, University of Port Harcourt, Choba, Port Harcourt, Nigeria

  • Mechanical Engineering, Niger Delta University, Wilberforce Island, Nigeria

  • Mechanical Engineering, Nigeria Maritime University, Okerenkoko, Nigeria

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